4.8 Review

Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related applications

Journal

COORDINATION CHEMISTRY REVIEWS
Volume 254, Issue 5-6, Pages 555-607

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2009.08.006

Keywords

1,3,5-Triaza-7-phosphaadamantane; Water-soluble ligands; Coordination chemistry; X-ray crystallography; Catalysis; Medicinal chemistry

Funding

  1. AQUACHEM [MRTN-CT-2003-503864]
  2. HYDROCHEM [HPRN-CT-2002-00176]
  3. Ente Cassa di Risparmio di Firenze
  4. COST Action [D29]
  5. PhoSciNet [CM0802]
  6. MIUR
  7. Italian Ministry for Foreign Affairs

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This review paper covers the recent developments (2004-2009) on the tailored synthetic modifications and related coordination chemistry of the water-soluble cage-like aminophosphine ligand 1.3,5-triaza-7-phosphatricyclo-[3.3.1.1]decane (PTA), together with the new applications in the fields of catalysis, material science and medicinal chemistry. (C) 2009 Elsevier B.V. All rights reserved.

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