Journal
COORDINATION CHEMISTRY REVIEWS
Volume 254, Issue 5-6, Pages 456-469Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2009.07.023
Keywords
C-H arylation; C-C coupling; Metal catalysis; Biaryls; Teraryls
Categories
Funding
- MIUR
- University of Parma
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The present review refers to catalytic methods to arylate arene or heteroarene compounds. The resulting compounds are ubiquitous in biology and in pharmaceuticals or fine chemicals production. Until a few decades ago they were prepared according to laborious procedures often involving a series of steps all requiring product isolation. Catalytic methods are much simpler and convenient and often consist of one-pot procedures leading to highly selective reactions. The reaction types described here encompass intermolecular as well as intramolecular reactions. Assistance by chelating groups, heteroatoms and metallacycles are considered for metal-catalyzed reactions not involving the use of oxygen or stoichiometric oxidants. (C) 2009 Elsevier B.V. All rights reserved.
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