Journal
COORDINATION CHEMISTRY REVIEWS
Volume 254, Issue 5-6, Pages 608-634Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2009.09.008
Keywords
Ansa compounds; Transition metals; Constrained geometry catalysts; Catalyst design; Epoxidation
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Funding
- International Graduate School for Science and Engineering (IGSSE)
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An overview of eta(5),eta(1)-coordinated transition metal ansa complexes is given. These compounds bear one or more coordinated cyclopentadienyl moieties connected with a eta(1)-bridging sigma-bonded carbon chain featuring a length of at least two carbon atoms. Synthetic approaches, as well as characterisation and applications are described. (C) 2009 Elsevier B.V. All rights reserved.
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