Journal
COORDINATION CHEMISTRY REVIEWS
Volume 253, Issue 9-10, Pages 1439-1457Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2008.10.010
Keywords
Electron transfer; Charge-separation; Donor-acceptor systems; Electronic coupling; Photochemistry; Excited state; Molecular wires; Supramolecular chemistry; Artificial photosynthesis; Transient absorption spectroscopy; Transient infrared spectroscopy
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Funding
- Swiss National Science Foundation
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This review article summarizes the research progress made since the year 2000 in the field of long-range electron transfer with synthetic systems that use d(6) or d(8) metal complexes as photosensitizers. This includes charge transfer over distances greater than 10 angstrom in both covalent and noncovalent donor-bridge-acceptor systems. Metal complexes of Ru(II), Os(II), Re(I), Ir(III), Ir(I), and Pt(II) are considered. (C) 2008 Elsevier B.V. All rights reserved.
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