Journal
COORDINATION CHEMISTRY REVIEWS
Volume 252, Issue 15-17, Pages 1798-1818Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.10.021
Keywords
fluxionality; sigmatropic rearrangements; haptotropic rearrangements; dynamic NMR; organometallic complexes; sigmatropic shifts
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This review describes two kinds of fluxionality in organometallic compounds: rearrangements proceeding via breaking and reformation of either sigma-(sigmatropic rearrangements) or pi-bonds (haptotropic rearrangements). (C) 2008 Elsevier B.V. All rights reserved.
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