Journal
COORDINATION CHEMISTRY REVIEWS
Volume 252, Issue 8-9, Pages 1007-1026Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2008.01.032
Keywords
metallosupramolecular networks; metal-organic frameworks; coordination polymers; gas storage; gas separation; guest binding; sensors; macrocyclic complexes; secondary building units; self-assembly; solvothermal reactions; selectivity
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Design and synthetic strategies for the construction of porous metallosupramolecular networks are presented. The porous metallosupramolecular networks show various functions such as gas adsorption, molecular recognition, ion exchange, sensing, and production of metal nanoparticles. Their specificities depend on the pore shape, size, and chemical environments of the voids or channels. In this review, relationship between the structures and functions is discussed. (c) 2008 Elsevier B.V. All rights reserved.
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