Journal
COORDINATION CHEMISTRY REVIEWS
Volume 252, Issue 15-17, Pages 1592-1612Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.11.029
Keywords
molybdenum; tungsten; alkyl ligands; cyclopentadienyl ligands; oxido ligands; aqueous organometallic chemistry
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The chemistry of organomolybdenum. and -tungsten compounds in high oxidation states (mostly V and VI) is reviewed, with special attention on the behaviour in protic media and with respect to protic reagents. The high metal-carbon bond covalency imparts a great degree of inertness to these bonds relative to protonolysis. Hence, extensive chemistry in a wide variety of media and with protic reagents is possible without affecting the metal-(hydrocarbyl ligand) interactions. This article does not cover metallocene [i.e. bis(cyclopentadienyl)], alkylidene and alkylidyne derivatives, that have been extensively covered in other recent reviews. (C) 2007 Elsevier B.V. All rights reserved.
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