Journal
JOURNAL OF MOLECULAR SPECTROSCOPY
Volume 318, Issue -, Pages 53-63Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jms.2015.10.006
Keywords
Microwave spectroscopy; Internal rotation; Methyl rotation; Large amplitude motion
Ask authors/readers for more resources
A re-examination of rotational line positions for toluene is reported, motivated by the recent observation that the methyl internal rotor states are perturbed by torsion-vibration coupling to vibrational mode M-20 (Gascooke et al., 2015). We demonstrate that the data can be fit equally well including or excluding torsion-vibration coupling. The torsion-vibration model required to account for the torsional band positions is thus shown to be consistent with the rotational line positions reported. It is found that including torsion-vibration coupling leads to changes in the values of the rotational and torsional constants, most significantly for A(F), A'(F), F and V-6, as well as the higher order constants, with those involving powers of m, K and their cross-terms most affected. Expressions for these effects are provided based on a perturbation expansion, which shows the links between the two models. A primary indicator for the presence of torsion-vibration coupling is A'(F). being significantly different to the rotational constant for the frame, A(F), and changing with m. Examination of published A'(F)/A(F) ratios for several substituted toluenes suggests that torsion-vibration coupling is widespread in such molecules. Torsion-vibration coupling has been directly observed through local perturbations to torsional levels in substituted toluenes with both 3- and 6-fold torsion potentials, indicating that it will also affect rotational and torsional constants in molecules with a 3-fold barrier. This indicates that the assumption that the small amplitude vibrations can be ignored when considering the large amplitude methyl rotation requires reassessment. (C) 2015 Elsevier Inc. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available