Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 398, Issue -, Pages 17-25Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2014.11.015
Keywords
Polyoxometalates; Metal organic framework; Deep desulfurization; Heterogeneous catalyst; Oxidation
Categories
Funding
- Razi University Research Council
- Iran National Science Foundation (INSF)
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Three hybrid composite materials were prepared by H3PW12O40 (PW), H3PMo12O40 (PMo) and H3SiW12O40 (SiW) into the porous metal-organic framework Cu-3(BTC)(2) (HKUST-1). The catalyst was characterized by various techniques including powder X-ray diffraction, FT-IR, SEM/EDX and successfully used for the selective oxidation of sulfides. Cyclic voltammetry was further used for the investigation of the redox behavior of this catalyst. Catalytic oxidation of the sulfur-containing model oil was also studied under optimized conditions. The oxidation desulfurization (ODS) system containing the catalyst could be recycled at least four times with only a slight decrease in the catalytic performance. The stability of the catalyst after the catalytic cycles was confirmed by several techniques. (C) 2014 Elsevier B.V. All rights reserved.
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