Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 407, Issue -, Pages 53-59Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2015.06.018
Keywords
Metal-organic frameworks; Heterogeneous catalysis; Aerobic oxidation; Copper catalysis
Categories
Funding
- National High Technology Research and Development Program of China [2013AA031702]
- Fundamental Research Funds for the Central Universities [FRF-TP-14-006A1]
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The three-dimensional Zr-based metal-organic framework UiO-66-NH2 was functionalized with salicylaldehyde using a post-synthetic modification (PSM) strategy, and then three kinds of copper (II) salts were successfully immobilized onto the surface of the amino-functionalized Zr-MOF. The SEM and PXRD results showed that the morphology and structure of Zr-MOF were retained after multiple transformations. The obtained UiO-66-Sal-CuCl2 catalyst exhibited excellent activity for the selective aerobic oxidation of primary aromatic alcohols using molecular oxygen as the oxygen source. Furthermore, the UiO-66-Sal-CuCl2 catalyst showed a good cycle performance. (C) 2015 Elsevier B.V. All rights reserved.
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