Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 408, Issue -, Pages 221-227Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2015.07.024
Keywords
Catalytic oxidation; Benzene; Manganese; Reaction mechanism
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Funding
- Natural Science Foundation of China [21177129]
- Chinese Academy of Sciences [XDB05050100]
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MOx/TiO2 composites with various metal species (M = Mn, Ce, Co, Fe) were synthesized and employed as in the catalytic oxidation of benzene. Among those materials, MnOx/TiO2 showed the highest catalytic efficiency. The catalytic activities of MnOx/TiO2 with different MnOx contents were also studied. XRD, BET, SEM, TEM, and XPS characterizations were conducted to analyze the physiochemical properties of the MnOx/TiO2 catalysts. Moreover, the reaction mechanism of benzene oxidation over MnOx/TiO2 was studied through the in situ FTIR experiments. (C) 2015 Elsevier B.V. All rights reserved.
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