4.1 Article

A novel method for the reduction of sulfoxides with the N,N,N′,N′tetrabromobenzene-1,3-disulfonamide (TBBDA)/PPh3 system

Journal

COMPTES RENDUS CHIMIE
Volume 17, Issue 10, Pages 1002-1006

Publisher

ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2013.11.006

Keywords

Deoxygenation; Reduction; Triphenylphosphine; Sulfides; Sulfoxides; TBBDA

Funding

  1. Bu-Ali Sina University, Center of Excellence and Development of Chemical Methods (CEDCM)

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A new method is described for the reduction of sulfoxides to sulfides using N,N,N',N'-tetrabromobenzene-1,3-disulfonamide [TBBDA] in combination with triphenylphosphine. Good to excellent yields, short reaction times, high efficiency and facile isolation of the desired products are the advantages of this method. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

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