Journal
COMPTES RENDUS CHIMIE
Volume 16, Issue 11, Pages 1035-1041Publisher
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2013.03.008
Keywords
9H-xanthene; Bisphenol; One-pot; Solvent-free; pTSA
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Funding
- Research Council of Arak University
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A simple and efficient procedure for the synthesis of 9H-xanthene or bisphenol derivatives has been developed by one-pot condensation of xylenols with aromatic aldehydes in the presence of p-toluenesulfonic acid (pTSA) as a catalyst under solvent-free conditions at 100 degrees C. It is noteworthy that the condensation reaction of 3,5-xylenol with aldehydes produces 9H-xanthene derivatives, while the reaction with other xylenols leads to the corresponding bisphenol derivatives. Different types of aromatic aldehydes are used in the reaction and in every case the products were obtained in good to excellent yields. The structures of these compounds were established on the basis of IR, H-1 NMR, C-13 NMR and CHN data. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
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