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Recent advances in the homogeneous polymerisation of olefins mediated by nickel complexes

Journal

COMPTES RENDUS CHIMIE
Volume 16, Issue 6, Pages 573-579

Publisher

ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2012.12.015

Keywords

Polymerisation; Nickel; Nickel complexes; Coordination compounds; Nickel clusters; MAO activation; Stereo-regular; Syndio-tactic polymers

Funding

  1. Ryerson University
  2. MaRS Innovation
  3. NSERC (Canada)

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A brief overview is presented on recent advances in the application of nickel coordination complexes as mediators of olefin polymerisation; in some cases involving stereo-regular polymer formation where appropriate. Emphasis is also given on recent findings concerning di- and tri-nuclear Ni clusters with details on ethylene, methyl methacrylate or styrene-based monomer polymerisations. (C) 2012 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

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