Journal
COMPTES RENDUS CHIMIE
Volume 14, Issue 2-3, Pages 149-166Publisher
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2010.04.003
Keywords
Cyclodextrin; Aqueous organometallic catalysis; Nanoparticles; Supported metals; Metal powder
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Funding
- ministere de l'Enseignement Superieur et de la Recherche
- Centre national de la recherche scientifique (CNRS)
- institut de recherche en environnement industriel (IRENI)
- Agence nationale de la recherche (ANR)
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During these last years, cyclodextrins have greatly contributed to the development of catalytic processes in water. These cyclic oligosaccharides composed of 6(alpha), 7(beta) or 8(gamma) glucopyranose units improve the mass transfer in aqueous-organic two-phase systems and are useful compounds to design new catalysts. Thus, chemically modified cyclodextrins can be used to: (1) significantly increase the rate and selectivity of reactions catalyzed by water-soluble organometallic complexes; (2) design new water-soluble ligands for aqueous organometallic catalysis; (3) stabilize catalytically active noble metal nanoparticles in water; (4) facilitate reactions catalyzed by supported metals or metallic powder in water. (C) 2010 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
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