4.1 Article Proceedings Paper

Dry reforming of methane in the presence of ruthenium-based catalysts

Journal

COMPTES RENDUS CHIMIE
Volume 12, Issue 6-7, Pages 748-753

Publisher

ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2008.10.021

Keywords

Methane reforming; CO2; Ruthenium; Hydrogen production; Alumina; Ceria

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The catalytic activities of ruthenium-based catalysts (5 wt% Ru) supported on alumina, ceria and ceria/alumina with different proportions of ceria (nCe10Al, n = 1, 3, 5; n = atomic ratio) were studied for the methane reforming reaction with CO2 (CH4/CO2 = 1) in the temperature range of 400-800 degrees C. Evaluation of coke deposited after the reaction showed carbon deposition on Ru catalysts supported on CeO2, 1Ce10Al and 3Ce10Al, but not on Ru/Al2O3 and Ru/5Ce10Al. Moreover, the sample Ru/5Ce10Al exhibited a higher activity than the other catalysts. To cite this article: M. Safariamin et al., C R. Chimie 12 (2009). (C) 2009 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

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