Journal
COMPTES RENDUS CHIMIE
Volume 11, Issue 8, Pages 805-817Publisher
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2008.01.019
Keywords
electrocatalysts; hydrogen oxidation; hydrogen production; proton relays; nickel; iron
Categories
Ask authors/readers for more resources
The paper presents a review of recent studies of complexes of Ni(II) and Fe(II) coordinated by diphosphine ligands with amine bases incorporated into the ligand chelate rings. The role of the bases in the second coordination sphere in mediating rapid intramolecular M-H/N-H exchange as well as intermolecular exchange with protons and in promoting the coupling of proton- and electron-transfer processes has been studied. Factors that favor efficient proton relay properties for the pendant amines have been established and the information has been used to develop efficient electrocatalysts for both hydrogen oxidation and production.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available