Journal
COMPTES RENDUS CHIMIE
Volume 11, Issue 6-7, Pages 628-640Publisher
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2008.01.010
Keywords
phosphole; bridging phosphane; pi-conjugated systems; organic light emitting diodes; non-linear optics; supramolecular assemblies
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The synthesis and properties of organophosphorus pi-conjugated chromophores incorporating metallic ions are described. Their optical and electrochemical properties depend on the metal centre linked to the organophosphorus atom. Moreover, the introduction of metallic ions induces a control of the supramolecular organization of the organophosphorus pi-conjugated systems. The specific properties of these complexes make them valuable materials for organic light-emitting diodes and interesting building blocks for the tailoring of novel NLO-phores.
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