Multi-scale interlaminar fracture mechanisms in woven composite laminates reinforced with aligned carbon nanotubes

Aligned nanoscale fibers have been shown to provide inter and intralaminar reinforcement of fiber-reinforced polymer composites. In one hierarchical architecture, aligned carbon nanotubes (CNTs) grown on advanced microfibers in a woven ply creates a 'fuzzy fiber' reinforced plastic (FFRP) laminate. Here, the mechanisms of Mode I fracture toughness enhancement for such laminates are elucidated experimentally by varying the type of epoxy and aligned CNT length. Reinforcement effectiveness is found to vary from reduced initiation toughness to over 100% increase in steady-state fracture toughness, depending upon the interlaminar fracture mechanisms. Fracture-surface morphology investigations reveal that interlaminar toughness enhancement is significantly less for an aerospace infusion resin than that for a much tougher hand lay-up marine epoxy. Long (similar to 20 micron) aligned CNTs add significant toughness in steady state (>1 kJ/m(2) increase for marine epoxy) via CNT pullout and by driving the crack through tortuous paths around and through microfiber bundles/tows, whereas shorter CNTs produce less toughening (or even reduced toughness in aerospace epoxy), which is attributed to increased microfiber-matrix cohesive failure. These findings reveal the multi-scale nature of the aligned-CNT reinforced composite ply interface, and the mechanisms at work at the micro and nanoscales that influence the macroscopic behavior. These new insights provide impetus for using aligned CNTs to tailor microfiber polymer composites by adjusting microfiber orientation, steering cracks through tortuous paths, and maximizing fracture surface area through both microfiber and nanofiber pullout. (C) 2014 Elsevier Ltd. All rights reserved.