Journal
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Volume 558, Issue -, Pages 95-102Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2018.08.068
Keywords
Nanoenzyme; Supra-amphiphile; Self-assembly; Vesicle; Cucurbit[8]uril
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Funding
- Natural Science Foundation of China [51573100, 91527302]
- Educational Commission of Liaoning Province, China [L2016013]
- Doctoral Scientific Research Foundation of Liaoning Science and Technology Department, China [201601203]
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Self-assembled vesicles are constructed based on supra-amphiphiles formed by cucurbit[8]uril and its two guest molecules. By modifying one of the guest molecules, an artificial nanohydrolase is constructed. An enhancement of catalytic activity for hydrolysis of 4-nitrophenyl acetate is observed, which is attributed to the enrichment effect of substrate around catalytic sites through the molecular recognition.
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