Journal
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Volume 430, Issue -, Pages 58-64Publisher
ELSEVIER
DOI: 10.1016/j.colsurfa.2013.04.001
Keywords
Anionic surfactants; Ionic liquids; Micelles; Pyrene fluorescence; Conductivity; Cmc
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Funding
- UGC, India
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Changes in the micellization behavior of an anionic surfactant sodium dodecylsulfate (SDS) in aqueous solutions have been investigated at varying concentration of hydrophobic ionic liquid 3-methy-1-pentylimidazolium hexafluorophosphate [C(5)mim][PF6] using techniques like conductometry, densiometry and speed of sound at a temperature range of 298.15-318.15 K. Critical micelle concentration (cmc) of SDS increases upon addition of [C(5)mim][PF6], which is also evidenced from fluorescence spectra of pyrene probe. Presence of solvophobic interactions is proposed to be the reason for these observations. (C) 2013 Elsevier B.V. All rights reserved.
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