Journal
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Volume 354, Issue 1-3, Pages 279-283Publisher
ELSEVIER
DOI: 10.1016/j.colsurfa.2009.08.002
Keywords
Nacre; Thin films; Calcium carbonate; Block copolymer; Monolayers
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG) International Materials World Network (MWN)
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Nacre-type organic/inorganic hybrid multilayers can be fabricated through a continuous polymer-induced liquid precursor (PILP) layer formed underneath a poly(styrene)-block-poly(acrylic acid) (PS-b-PAA) block copolymer monolayer. Subsequent Layer-by-Layer transfer of block copolymer/PILP films leads to a multilayer with organic-inorganic hybrid architecture. The subsequent annealing process transforms the PILP layers into layers of polycrystalline CaCO3, which morphologically resemble that of biogenic nacre. (C) 2009 Elsevier B.V. All rights reserved.
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