Adsorption of Remazol Red 3BS from aqueous solutions using APTES- and cyclodextrin-modified HMS-type mesoporous silicas

The removal of Remazol Red 3BS (C.I. 239) dye by HMS ordered mesoporous silica, aminopropyl-modified HMS (HMS-NH2) and beta-cyclodextrin-modified HMS (HMS-CD) materials was studied in the present work. The modified materials were functionalized in situ by adding the organic modifiers (3-aminopropyltriethoxysilane and a silylated derivative of MCT-beta-CD) in the synthesis mixture and using dodecylamine as the mesopore structure directing agent. The successful incorporation of aminopropyl groups in HMS-NH2 and of cyclodextrin moieties in HMS-CD was verified by means of FT-IR spectroscopy, elemental analysis and N-2 porosimetry. The HMS-CD material exhibited significantly higher adsorption capacity compared to that of the HMS-NH2 material, while the parent HMS mesoporous silica showed negligible adsorption capability. The maximum adsorption capacities obtained (at the optimum pH 2) on the basis of the Langmuir analysis were 0.28 mmol/g for HMS-CD and 0.14 mmol/g for HMS-NH2. It Was shown that the HMS-CD sorbent can be effectively regenerated by the surfactant-enhanced regeneration method using SDS and that can be reused without significant loss of its adsorption capabilities. (C) 2009 Elsevier B.V. All rights reserved.