Journal
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Volume 317, Issue 1-3, Pages 751-755Publisher
ELSEVIER
DOI: 10.1016/j.colsurfa.2007.10.030
Keywords
nanocomposite; polysiloxane; latex; miniemulsion; montmorillonite; polymerization
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Montmorillonite clay was encapsulated within a fluorinated cyclosiloxane (1,3,5-tris(trifluoropropylmethyl)cyclotrisiloxane) to give stable water-based nanocomposite latex, using miniemulsion polymerization technique. The resulting composite latex was characterized by transmission electron microscopy (TEM), dynamic light scattering (DLS) and RX diffraction. The particles stability was investigated by sedimentation and surface tension measurements. An efficient cationic/nonionic surfactant mixture was used in order to achieve the best compatibility with the monomer. TEM and RX data revealed the partial embedding of montmorillonite in the spherical polymer based nanoparticles. According to DLS measurements, the encapsulated clay particles conserve their size throughout the polymerization process. The melt processing of poly(trifluoropropylmethylsiloxane) matrix to encapsulate the montmorillonite clay was also carried out for comparison purposes. (C) 2007 Elsevier B.V. All rights reserved.
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