Journal
COLLOID AND POLYMER SCIENCE
Volume 291, Issue 8, Pages 1989-1997Publisher
SPRINGER
DOI: 10.1007/s00396-013-2939-4
Keywords
Cross-link; PVDF; Crystallization; Interface; Dielectric
Categories
Funding
- National Natural Science Foundation of China [21274057, 20825415]
- Fundamental Research Funds for the Central Universities [1103020504]
- Scientific Research Foundation of Graduate School of Nanjing University [2010CL06]
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Photoinitiated cross-linking of poly(vinylidene fluoride-co-chlorotrifluoroethylene) can offer a significant increase in electric energy storage capacity. This improvement is related to the structural changes in the copolymer crystals brought by cross-linking. Cross-linking favors formation of polar crystalline phase, drastic reduction of spherulite sizes, and increase in copolymer inner interface area. This copolymer case demonstrates the greatly enhanced energy storage behavior, including increased discharge energy density at reduced field strength, and improved capacitor efficiency at relatively high degree of cross-linking, which may facilitate a better design for polymer dielectric materials in their application of high energy density capacitors.
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