Journal
COLLOID AND POLYMER SCIENCE
Volume 290, Issue 18, Pages 1943-1947Publisher
SPRINGER
DOI: 10.1007/s00396-012-2815-7
Keywords
Nylon-6; Crystallization; Hydrogen bonds
Categories
Funding
- National Foundation of Nature Science [21072221, 21172252]
- Graduate University of CAS [095101CY00]
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Hydrogen bonds exist in many polymer systems and play a large role in the physical and chemical properties. In this study, nylon-6, which consists of repeated amide groups and contains large number of hydrogen bonds, is chosen as an example. Meanwhile, the oxidized unzipped MWCNTs (mu CNTs) with oxygenated species such as carboxyl and hydroxyl groups are used as mediator to regulate the crystallization process of nylon-6 thin films. In-site experimental techniques, including Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy, and polarized optical microscopy were utilized to get more direct insights on the crystallization mechanism of nylon-6 and mu CNTs systems.
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