4.4 Article

High mechanical strength hydrogels preparation using hydrophilic reactive microgels as crosslinking agents

Journal

COLLOID AND POLYMER SCIENCE
Volume 287, Issue 5, Pages 621-625

Publisher

SPRINGER
DOI: 10.1007/s00396-009-2018-z

Keywords

Hydrogels; Polymers; Microgels; Microstructure; Mechanical strength

Funding

  1. Shandong Province Middle-aged and Young Scientists Research Incentive Fund [2008BS04008]

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HRM (hydrophilic reactive microgels) hydrogels based on acrylamide and 2-acrylamido-2-methylpropane sulfonic acid were prepared using HRM as a new crosslinking agent. HRM containing double bonds (C=C) were obtained by chemically modifying hydrophilic microgels (HM) of acrylamide with 2-acrylamido-2-methylpropane sulfonic acid. The resulting HRM hydrogels had high compression strength, elasticity, and elongation under high water content. The excellent mechanical performance is a main result of the unique microstructure of the hydrogels that are crosslinked by HRM instead of the conventional crosslinking agents such as N,N'aEuromethylenebisacrylamide.

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