4.6 Article

Synthesis of Fe2O3-Ni(OH)2/graphene nanocomposite by one-step hydrothermal method for high-performance supercapacitor

Journal

JOURNAL OF MATERIALS SCIENCE
Volume 51, Issue 6, Pages 2877-2885

Publisher

SPRINGER
DOI: 10.1007/s10853-015-9596-6

Keywords

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Funding

  1. National Natural Science Foundation of China [U1401246, 51276044, 51502042]
  2. National Natural Science Foundation of Guangdong Province [U1401246]
  3. Science and Technology Program of Guangdong Province of China [2014B010106005, 2013B051000077, 2015A050502047]
  4. Science and Technology Program of Guangzhou City of China [201508030018]

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Graphene-based nanocomposites have been one of the most attractive electrode materials of supercapacitors. But in most cases, graphene-based nanocomposites always use single nanoparticle as active material, which cannot meet the increasing demand for next generation of energy storage devices. In the present paper, we prepared Fe2O3-Ni(OH)(2)/graphene nanocomposite by simple one-step hydrothermal method. The dual-particle system reveals a synergistic effect between Fe2O3 and Ni(OH)(2), i.e., Ni(OH)(2) can enhance the electrical conductivity of Fe2O3, and then Fe2O3 can act as electrical conductivity bridges between Ni(OH)(2) nanoparticles and RG. As a result, the Fe2O3-Ni(OH)(2)/graphene nanocomposite presents impressing electrochemical performance, including high specific capacitance (similar to 857 F/g), good rate capability, and outstanding cycling stability (after 5000 cycles, 100 % retention).

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