Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 21, Pages 6251-6254Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501616
Keywords
electrocatalysts; nonprecious metal catalysts; overall water splitting; potentiodynamic deposition
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Funding
- Governor's Energy Leadership Scholars Grant of the State of Utah
- Utah State University
- Principle Energy Issues Program of the State of Utah
- Div Of Civil, Mechanical, & Manufact Inn
- Directorate For Engineering [1337932] Funding Source: National Science Foundation
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One of the challenges to realize large-scale water splitting is the lack of active and low-cost electrocatalysts for its two half reactions: H-2 and O-2 evolution reactions (HER and OER). Herein, we report that cobalt-phosphorous-derived films (Co-P) can act as bifunctional catalysts for overall water splitting. The as-prepared Co-P films exhibited remarkable catalytic performance for both HER and OER in alkaline media, with a current density of 10mAcm(-2) at overpotentials of -94mV for HER and 345mV for OER and Tafel slopes of 42 and 47mV/dec, respectively. They can be employed as catalysts on both anode and cathode for overall water splitting with 100% Faradaic efficiency, rivalling the integrated performance of Pt and IrO2. The major composition of the as-prepared and post-HER films are metallic cobalt and cobalt phosphide, which partially evolved to cobalt oxide during OER.
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