Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 28, Pages 8208-8212Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201503153
Keywords
methylammonium lead triiodide; perovskites; solar cells; spectroscopy; stability
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Funding
- Engineering and Physical Sciences Research Council (EPSRC) [EP/H040218/2, EP/K010298/1]
- European Community's Seventh Framework Programme (Nanomatcell) [308997]
- Austrian Science Fund (FWF) [J3515-N20]
- EPSRC [EP/K010298/1, EP/M023532/1] Funding Source: UKRI
- Austrian Science Fund (FWF) [J 3515] Funding Source: researchfish
- Engineering and Physical Sciences Research Council [2050414, EP/M023532/1, EP/K010298/1] Funding Source: researchfish
- Austrian Science Fund (FWF) [J3515] Funding Source: Austrian Science Fund (FWF)
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In this paper we report on the influence of light and oxygen on the stability of CH3NH3PbI3 perovskite-based photoactive layers. When exposed to both light and dry air the mp-Al2O3/CH3NH3PbI3 photoactive layers rapidly decompose yielding methylamine, PbI2, and I-2 as products. We show that this degradation is initiated by the reaction of superoxide (O-2(-)) with the methylammonium moiety of the perovskite absorber. Fluorescent molecular probe studies indicate that the O-2(-) species is generated by the reaction of photoexcited electrons in the perovskite and molecular oxygen. We show that the yield of O-2(-) generation is significantly reduced when the mp-Al2O3 film is replaced with an mp-TiO2 electron extraction and transport layer. The present findings suggest that replacing the methylammonium component in CH3NH3PbI3 to a species without acid protons could improve tolerance to oxygen and enhance stability.
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