Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 9, Pages 2801-2805Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408891
Keywords
alkenylation; CH functionalization; photoredox catalysis; superoxide; visible light
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Funding
- European Research Council under the European Union/ERC [617044]
- European Research Council (ERC) [617044] Funding Source: European Research Council (ERC)
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A combination of ruthenium and photoredox catalysis allowed the ortho olefination of phenols. Using visible light, the direct CH functionalization of o-(2-pyridyl)phenols occurred, and diverse phenol ethers were obtained in good yields. The regeneration of the ruthenium catalyst was accomplished by a photoredox-catalyzed oxidative process.
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