Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 37, Pages 10975-10979Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201504757
Keywords
carbene; C-H activation; fluorophore; rhodium; triazole
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Funding
- Korea Research Foundation [NRF-2014R1A6A3A03057520]
- European Research Council under European Community's Seventh Framework Program (FP7)/ERC [25936]
- Alexander von Humboldt Foundation
- DFG [SFB-TTR61, C07]
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The first CH bond activation with pyridotriazoles as coupling partners is presented using a Rh-III catalyst. The pyridotriazoles can be used as new carbene precursors in CH activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metalions.
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