Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 49, Pages 14965-14969Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508495
Keywords
copper; fluorine; heterocycles; sulfur; synthetic methods
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Funding
- National Natural Science Foundation of China [21476116, 21402093]
- Natural Science Foundation of Jiangsu [BK20141394]
- FRFCU [30920140122003]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Centre for Green Chemistry at the University of Massachusetts Boston
- Center for Advanced Materials and Technology in Nanjing University of Science and Technology
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A new method for CF3SO2Na-based direct trifluoromethylthiolation of C(sp(2))-H bonds has been developed. CF3SSCF3 is generated in situ from cheap and easy-to-handle CF3SO2Na, and in the presence of CuCl can be used for electrophilic trifluoromethylthiolation of indoles, pyrroles, and enamines. The method has been extended to perfluoroalkylthiolation reactions using RfSO2Na.
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