Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 2, Pages 785-789Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509996
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Funding
- Scripps Research Institute
- NIH (NIGMS) [2R01GM084019]
- NSF under the Science Across Virtual Institutes program as part of the CCI Center for Selective C-H Functionalization [CHE-1205646]
- Grants-in-Aid for Scientific Research [15J04925] Funding Source: KAKEN
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1205646] Funding Source: National Science Foundation
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A quinoline-based ligand effectively promotes the palladium-catalyzed borylation of C(sp(3))-H bonds. Primary beta-C(sp(3))-H bonds in carboxylic acid derivatives as well as secondary C(sp(3))-H bonds in a variety of carbocyclic rings, including cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated. This directed borylation method complements existing iridium(I)-and rhodium(I)-catalyzed C-H borylation reactions in terms of scope and operational conditions.
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