Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 21, Pages 6265-6269Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500201
Keywords
asymmetric catalysis; CH activation; chirality; palladium; Pligands
Categories
Funding
- National Basic Research Program of China (973 Program) [2010CB833300]
- NSFC [20902099, 21172238, 21472218]
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A palladium-catalyzed enantioselective CH arylation of N-(o-bromoaryl)-diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a P-stereogenic center. The method provides good enantioselectivities and high yields. The products were readily transformed into P-chiral biphenyl monophosphine ligands.
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