Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 47, Pages 14137-14140Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507087
Keywords
C-H activation; indoles; isocyanates; manganese; reaction mechanisms
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Funding
- European Research Council under the European Community/ERC [307535]
- Chinese Scholarship Program
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A versatile manganese(I) catalyst was employed in C-H aminocarbonylation reactions of heteroarenes with aryl as well as with alkyl isocyanates using a removable directing group approach. Detailed experimental mechanistic studies were suggestive of an organometallic C-H manganesation step, followed by a rate-determining migratory insertion.
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