Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 23, Pages 6795-6799Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502155
Keywords
heterogeneous catalysis; hydrolysis; metal-organic frameworks; MOF plug-flow reactor; nerve agents
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Funding
- DTRA [HDTRA-1-10-0023]
- MRSEC program of the National Science Foundation at the Materials Research Center of Northwestern University [DMR-1121262]
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A nerve-agent simulant based on a phosphate ester is hydrolyzed using a MOF-based catalyst. Suspensions of MOF-808 (6-connected), a material featuring 6-connected zirconium nodes, display the highest hydrolysis rates among all MOFs that have been reported to date. A plug-flow reactor was also prepared with MOF-808 (6-connected) as the active layer. Deployed in a simple filtration scheme, the reactor displayed high hydrolysis efficiency and reusability.
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