Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 20, Pages 5994-5998Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501195
Keywords
cyclic voltammetry; dyes/pigments; energy conversion; polycycles; solar cells
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Funding
- National 973 Program [2011CBA00702, 2015CB932204]
- National Science Foundation of China [51125015, 51473158, 91233206]
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Reported are two highly efficient metal-free perylene dyes featuring N-annulated thienobenzoperylene (NTBP) and N-annulated thienocyclopentaperylene (NTCP), which are coplanar polycyclic aromatic hydrocarbons. Without the use of any coadsorbate, the metal-free organic dye derived from the NTCP segment was used for a dye-sensitized solar cell which attained a power conversion efficiency of 12% under an irradiance of 100 mW cm(-2), simulated air mass global (AM1.5G) sunlight.
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