Magnetic and microwave absorption properties of rare earth ions (Sm3+, Er3+) doped strontium ferrite and its nanocomposites with polypyrrole

M-type strontium ferrite substituted by RE (RE=Srn(3+), Er3+) were prepared via a sol-gel method. Polypyrrole (PPy)/ferrite nanocomposites (with 20 wt% ferrite) were prepared by in situ polymerization method in the presence of ammonium persulfate. Effect of the substituted RE ions on structure, magnetic properties and microwave absorption properties were investigated by X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and vector network analyzer. All XRD patterns show the single phase of strontium hexaferrite without other intermediate phases. The crystallite size of synthesized particle is within the range of 22.2-38.1 nm, The structural in character of the composites were investigated with FT-IR analysis. It shows that the ferrite successfully packed by PPy. TEM photographs show that the particle size had grown up to 50-100 nm after coating with PPy. In the magnetization for the PPY/SrSm0.3Fe11.7O19 (SrEr0.3Fe11.7O19) composites, the coercivity (H-c) of the composites both increased compared with the undoped composite while the saturation magnetization (M-s) appeared opposite change with different RE ions. Considering the electromagnetic loss and impedance matching comprehensively, the Er-doped ferrite/PPy composite got the better microwave absorption performance with the maximum RL value of -24.01 dB in 13.8 GHz at 3.0 mm. And its width (< - 10 dB) has reached 7.2 GHz which has covered the whole Ku band. (C) 2015 Elsevier B.V. All rights reserved.