Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 44, Pages 13045-13048Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201506273
Keywords
asymmetric catalysis; CH activation; green chemistry; oxygen; rhodium
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Funding
- National Natural Science Foundation of P. R. China [21272192, 21201143, 21472154]
- Program for Changjiang Scholars and Innovative Research Team of P. R. China (PCSIRT)
- National Thousand Talents Program of P. R. China
- Xiamen University
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A sustainable CC bond formation is merged with the catalytic asymmetric generation of one or two stereocenters. The introduced catalytic asymmetric cross-coupling of two Csp3H groups with molecular oxygen as the oxidant profits from the oxidative robustness of a chiral-at-metal rhodium(III) catalyst and exploits an autoxidation mechanism or visible-light photosensitized oxidation. In the latter case, the catalyst serves a dual function, namely as a chiral Lewis acid for catalyzing enantioselective enolate chemistry and at the same time as a visible-light-driven photoredox catalyst.
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