Journal
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
Volume 391, Issue -, Pages 75-82Publisher
ELSEVIER
DOI: 10.1016/j.jmmm.2015.04.092
Keywords
Monovalent substitution; Lanthanum manganites; Na concentration; Mixed valency; Magnetic inhomogeneity; Oxygen vacancy
Funding
- DST INSPIRE [DST/INSPIRE Fellowship/2010/236]
- BRNS [2011/34/7/BRNS/0596]
- Sultan Qaboos University for Research [IG/SCl/PHYS/14/03]
- DST, New Delhi via INSPIRE Faculty award
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Mixed valence manganite system with monovalent sodium substituted lanthanum manganites form the basis of the present work. Lanthanum manganites belonging to the series La1-xNa5MnO3 with x=0.5-0.9 were synthesized using modified citrate gel method. Variation of lattice parameters and unit cell volume with Na concentration were analyzed and the magnetization measurements indicated ferromagnetic ordering in all samples at room temperature. Low temperature magnetization behavior indicated that all samples exhibit antiferromagnetism along with ferromagnetism and it has also been observed that antiferromagnetic ordering dominates ferromagnetic ordering as concentration is increased. Evidence for such a magnetic inhomogeneity in these samples has been confirmed from the variation in Mn3+/Mn4+ ion ratio from X-ray Photoelectron Spectroscopy and from the absorption peak studies using Ferromagnetic Resonance Spectroscopy. (C) 2015 Elsevier B.V. All rights reserved.
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