Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 12, Pages 3712-3716Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410954
Keywords
arenes; C-H functionalization; halogen bonding; pentafluoroethylation; trifluoromethylation
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Funding
- European Community
- NSF [CHE-0952753]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0952753] Funding Source: National Science Foundation
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A family of practical, liquid trifluoromethylation and pentafluoroethylation reagents is described. We show how halogen bonding can be used to obtain easily handled liquid reagents from gaseous CF3I and CF3CF2I. The synthetic utility of the new reagents is exemplified by a novel direct arene trifluoromethylation reaction as well as adaptations of other perfluoroalkylation reactions.
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