Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 17, Pages 5084-5087Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500129
Keywords
aggregation; carboranes; crystal growth; luminescence; solid-state structures
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Funding
- MEXT [24102013]
- Grants-in-Aid for Scientific Research [24102013, 15H03856] Funding Source: KAKEN
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An o-carborane-based anthracene was synthesized, and single crystals, with incorporated solvent molecules, were obtained from the CHCl3, CH2Cl2, and C6H6 solutions. The anthracene ring in the crystal is highly distorted by the formation of a p-stacked dimer between the anthracene units. The crystals exhibited a variety of emission behaviors such as aggregation-induced emission (AIE), crystallization-induced emission (CIE), aggregation-caused quenching (ACQ), and multichromism.
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