Journal
JOURNAL OF LUMINESCENCE
Volume 158, Issue -, Pages 333-339Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2014.10.005
Keywords
Lanthanum aluminosilicate glass; Fluorescence; Samarium III; Multi-phonon quenching
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Funding
- European Social Fund (ESF) through the Thuringian Ministry of Economy, Employment and Technology [2011 FGR 0122]
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In this paper we report on the fluorescence quenching behavior of Sm3+ doped lanthanum alumino silicate glasses in dependence of the Sm3+ concentration and chemical composition of the glasses. In general, lanthanum alumino silicate glasses offer relatively low intrinsic Sm3+ fluorescence lifetimes between 2.3 and 2.7 ms. Independently on the doping concentration, the lifetime decreases with increasing refractive index and increasing lanthanum concentration of the glasses. For a low doping concentration of 0.1 x 10(20) Sm3+ per cm(3) (approx. 0.025 mol% Sm2O3) the measured fluorescence lifetimes are very close to the radiative lifetimes which were calculated using the Judd-Ofelt analyses. For higher doping concentrations, such as 1 x 10(2) and 3 x 10(2) Sm3+ per cm(3), concentration quenching becomes obvious. For these higher concentrations, the non-radiative relaxation of the excited state can be seen as a mixture of cross-relaxation processes and OH- quenching. Both processes mainly occur at higher concentrations and do not influence the fluorescence decay at low Sm3+ concentrations. By contrast, the maximum phonon energy of the glass network does not affect the radiative relaxation of Sm3+ at all. (C) 2014 Elsevier B.V. All rights reserved.
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