Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 47, Pages 14040-14043Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507839
Keywords
ceria-zirconia particles; heterogeneous catalysis; high-energy milling; oxygen storage; soot combustion
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Funding
- Regione Friuli Venezia Giulia
- MIUR (Futuro in ricerca, project SOLYST)
- ICREA Academia program
- MINECO [ENE2012-36368]
- Generalitat de Catalunya [2013 BP-B 00007]
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Engineering the interface between different components of heterogeneous catalysts at nanometer level can radically alter their performances. This is particularly true for ceria-based catalysts where the interactions are critical for obtaining materials with enhanced properties. Here we show that mechanical contact achieved by high-energy milling of CeO2-ZrO2 powders and carbon soot results in the formation of a core of oxide particles wrapped in a thin carbon envelope. This 2D nanoscale carbon arrangement greatly increases the number and quality of contact points between the oxide and carbon. Consequently, the temperatures of activation and transfer of the oxygen in ceria are shifted to exceptionally low temperatures and the soot combustion rate is boosted. The study confirms the importance of the redox behavior of ceriazirconia particles in the mechanism of soot oxidation and shows that the organization of contact points at the nanoscale can significantly modify the reactivity resulting in unexpected properties and functionalities.
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