Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 29, Pages 8498-8501Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502686
Keywords
heterostructures; hydrogen; overall water splitting; oxynitrides; photocatalysis
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Funding
- Basic Research Program of China (973 Program) [2014CB239403]
- Natural Science Foundation of China [21361140346, 21373210]
- Japan Society for the Promotion of Science (JSPS) [23000009]
- Hundred Talents Program of CAS
- Grants-in-Aid for Scientific Research [23000009] Funding Source: KAKEN
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An (oxy)nitride-based heterostructure for powdered Z-scheme overall water splitting is presented. Compared with the single MgTa2O6-xNy or TaON photocatalyst, a MgTa2O6-xNy/TaON heterostructure fabricated by a simple one-pot nitridation route was demonstrated to effectively suppress the recombination of carriers by efficient spatial charge separation and decreased defect density. By employing Pt-loaded MgTa2O6-xNy/TaON as a H-2-evolving photocatalyst, a Z-scheme overall water splitting system with an apparent quantum efficiency (AQE) of 6.8% at 420 nm was constructed (PtOx-WO3 and IO3- /I- pairs were used as an O-2-evolving photocatalyst and a redox mediator, respectively), the activity of which is circa 7 or 360 times of that using Pt-TaON or Pt-MgTa2O6-xNy as a H-2-evolving photocatalyst, respectively. To the best of our knowledge, this is the highest AQE among the powdered Z-scheme overall water splitting systems ever reported.
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