Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 41, Pages 12134-12138Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201505926
Keywords
asymmetric catalysis; boron; copper; cross-coupling; synthetic methods
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Funding
- NSFC [21472184, 21272226, 21202160, 21402186]
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Presented is the first enantioselective copper-catalyzed 1,6-conjugate addition of bis(pinacolato) diboron to para-quinone methides. The reaction proceeds with excellent yields and good to excellent enantioselectivities, and provides an attractive approach to the construction of optically active gem-diarylmehtine boronic esters. Additionally, the subsequent conversion of the derived potassium trifluoroborates into triarylmethanes with highly enantiospecificity was realized.
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