Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 20, Pages 6051-6056Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201411972
Keywords
dispersion interactions; N-acenes; polymorphism; pyrenes; structure elucidation
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Funding
- Deutsche Forschungsgemeinschaft
- Fond der Chemischen Industrie
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A highly soluble pyrene-fused undecacene is realized by end-capping the rectilinear aromatic pi-plane with triptycenylene units. Besides the good solubility, the compound shows a high tendency to crystallize. Two polymorphs from dichlorobenzene and chloroform are described. In the polymorph from chloroform, half of the molecules are strongly bent out of the pi-plane by 26.4 degrees.
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