Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 27, Pages 7920-7923Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501538
Keywords
allenes; carbenes; copper; diazo compounds; flow chemistry
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Funding
- Cambridge Home and European Scholarship Scheme
- Swiss National Science Foundation
- Pfizer Worldwide Research and Development
- EPSRC [EP/K0099494/1, EP/K039520/1]
- EPSRC [EP/K009494/1, EP/K039520/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039520/1, EP/K009494/1] Funding Source: researchfish
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A copper-catalyzed coupling reaction between flow-generated unstabilized diazo compounds and terminal alkynes provides di- and trisubstituted allenes. This extremely mild and rapid transformation is highly tolerant of several functional groups.
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