Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 43, Pages 12669-12672Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201506446
Keywords
acylation; arenes; cross-coupling; palladium; reaction mechanisms
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Funding
- 973 project from the MOST of China [2015CB856600]
- NSFC [21272221, 21472179]
- Recruitment Program of Global Experts
- Fundamental Research Funds for the Central Universities [WK 2060190028, 2060190026]
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A palladium-catalyzed, norbornene-mediated Catellani ortho-acylation reaction was developed by the use of either acyl chlorides or acid anhydrides as acylation reagents. The addition of more than a stoichiometric amount of H2O is crucial for this transformation when acid chlorides are used, and kinetic studies indicate that the active acylation reagent is possibly an acid anhydride.
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